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Of course Buggy's, already confirmed

In terms of "willpower" it's stronger Luffy's, but when it comes to possessing better control over CoC I think it's safer to say both of them at equal level, because Rayleigh taught him nothing about Conqueror's Haki

Next chapter Kaido, Big Mom, Luffy and Kid use CoC at the same time and quite a lot of samurai and beast pirates on the live floor feel it and pass out