Onimaru said that Ryuma conquered his black blade throughout his history of combat with his swords.
Zoro has no history with enma, he inherited it 2 weeks ago and barely used it, if Zoro makes her black it is because Oden has already made Enma a sword strong enough for Zoro to just finish the...
Zoro will only be able to overcome/match him when he manages to turn Wado Ichimonji into a black sword, and that will only be in his final fight against Mihawk
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