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Hitsugaya's adult form can only be accessed after all of his Bankai's ice petals have fallen. (Not sure about that, it's been a long time since I read the manga) So it takes a considerable amount of time. But if I ignored that, yes, adult Hitsugaya would undoubtedly be in the most powerful...

1- Yamamoto Genryussai 2- Zaraki Kenpachi 3- Unohana Kenpachi 4- Azashiro Kenpachi 5- Kuroyashiki Kenpachi 6- Shinigami Aizen 7- Shunsui Kyoraku 8- Urahara Kisuke 9- Byakuya Kuchiki 10- Mayuri 11- Yoruichi 12- Ukitake 13- Hikifune