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Hyogoro literally said Luffy used a level above the haki he was using. Hyogoro was using barrier haki, Luffy went straight on internal damage.

Ryou is barrier haki or simple using haki on weapons just like Amazon Lily girls were doing or Zoro is doing since timeskip. Internal Damage is hitting from inside. That's why Luffy is touching Kaido on chapter 1000. If he was using barrier haki he wouldn't touch like Sentomaru did with him at...

This is internal damage. Not Ryou.

Nope. He used internal destruction never Ryou.

Luffy never showed he learned Ryou.