If badass means impressive for shounen readers, then Zoro is the most badass. He is normal human (with no DF) that have outstanding feats and record, more than most character ever done. He looks cool & induce reader's tension/adrenaline more.
By comparison, Luffy is the MC, have different body structure, and helped by destiny & luck a lot. If he did stuff impressively, that's because he is supposed to be. Even then, what he does is more charming than badass.
Sanji's feats is more vital, but those are mostly "supportive" / "defend" type accomplishments, so although his actions is important, it does not look "badass".