While with Haki you can touch and block attacks of Akainu who have far more AP then a oil soup and also have more degree temprature.
I think at least 30-40min using of full body haki could at least let him able to survive the oil soup without much taking damage.
I honestly don't think haki (specially armament) has to show up as hardening or nothing. The in between possibilities, even for unintentional use, are several.
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