Nah, its genuinely just visual flair. Lol. I can almost guarantee you there is nothing else to it than Oda thinking it looked cool, and wanting Zoro to have a slightly different look to his powers than other swordsmen.
The green flamey i'm pretty sure it's just because Oda likes flames and zoro's palette is green.
Luffy can use flames and he's red.
sanji uses blue flames now, since his main color is blue.
then zoro gets the green stuff.
If he and Killingham somehow survive Elbaf (I highly doub it), in the Final War Sommers might give the WG their own Zoro through the nightmares he's bound to have after this fight.
Those panels pretty much confirm that Zoro never use AdvCoC against Lucci.
The green flames are not AdvCoC but most likely CoA or a advanced version of foxfire style.
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