I think it’s a way Oda’s using to visualize this fusion of CoA & CoC that Sanji’s been able to acquire in attempt to manifest the ultimate defense.
Also another characteristic about it is the flame type pattern at the end which I think Oda’s utilized several times now when there is some some sort Armament Fusion going on. We’ve seen it with Luffy’s G4 when he combines armament with his rubber fruit. Big mom & also Kat but it’s always been a DF Armament fusion.
So I think that’s representative of Sanji’s current CoA + CoC fusion.
Lastly I did find it quite interesting that Oda made the blackening so obvious this time & even had Sanji disable his flames to flex it so could be that Oda wanted this to be a representation of black leg Sanji as opposed to just regular hardening hence why he didn’t put too much focus on highlight Sanji’s hardening but that’s just my guess though but with Sanji it’s clear that Oda’s quite meticulously with his writing so wouldn’t be surprised.
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