No, Gorosei didn't use ACoC till he performed at ACoC roar attack. Before than it was just normal haki.
Zoro is still a new conqueror. Neither the world nor the SH knows he's a conqueror. Characters has a reason to comment when he performs ACoC attacks.
It's confirmed. Zoro didn't use ACoC. Neither Jinbe nor Lucci commented on that power used.
Jinbe wasn't attacking Lucci to hurt him or knock him out. He was attacking the ground to create a smoke screen so the world elder wouldn't see where they went.
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