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Zoro is capable of recognizing a CoC burst but doing it himself might be a very different thing, i think the scene fits a lot better if zoro had awakened both CoC and AdCoC in that moment but oh well ..

Exactly, at the time i thought zoro didn't know he had CoC but now after the anime i think they have to make it like he knew he had CoC but was confused at Kaido's words because he didn't ( consciously) use it which is ehhhhhhh but it is what it is.

To me the only way it makes sense is that Kaido noticed his AdCoC because we saw that zoro didn't unleash the normal CoC haki blast and also because the attack did alot more damage to kaido than zoro's other attacks and the only other attack to scar kaido was Oden's AdCoC togen totsuka.

Why was Kaido surprised about zoro's CoC then if not for zoro using AdCoc ?