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I suppose in due time (likely by end of this fight) when he learns to wield Enma as if "it's as light as feather", he'd not need the catalyst specifically anymore (though it would make things easier, no doubt). But yeah, I don't think Asura was ACoC. Just that Zoro unlocked his regular CoC in...

Enma is a PU as it acts like a catalyst and helps him channel, that's the gimmick derived from its personality. Yet manifesting it and coating it is something Zoro can do by himself, as seen by other swords.

I mean the entire narrative of the chapter was Enma, and obviously Enma helped him channel his haki, and demanded more from him- which evenetually ended in Zoro releasing it all, but... ...he's definitely coating all three of his blades in haki at his will. Enma can't do that for him. Wait, is...