By Alignment I mean where does She fall on this:
On the lawful vs Chaos side.
She is very proudly boastful of her Samurai bloodline claiming she would not ask for Orochi's forgiveness for slapping him because it would be too insulting to her Samurai bloodline. So she displays great respect for the honor of noble bloodlines like hers here. This is lawful.
Later she seemingly shows more respect for Wano as a country than her bloodline when she's willing to part with a family heirloom by giving it to Zoro, a relative stranger, in exchange for Shusui, a national treasure, being left in its burial ground. This of course is also Lawful since adherence to the respect given to heirachy in authority is lawful and the Kozuki clan she respects is in service of Wano as a country.
Therefore I would say she's Lawful.
Next is the Good vs Evil part.
She put herself in harms way to save Toko multiple times and she says in her eyes the most despicable thing Orochi has done is prevent from expressing their grief and sorrow through the Smile fruits. This falls along Good since its self sacrifice and empathy.
She suffered from some sort of depression and remained mute after her parents died and Kawamatsu spent the time cheering her up until she was seemingly got over this. Then she ran away since she didn't want to see him waste away from starvation just to feed her which left Kawamatsu heartbroken obviously.
She saved Toko but said "her cheerfulness is what keeps her going" insinuating that she also specfically gains something (probably due to her previous depression) from having Toko around and she isn't entirely altruistic in her risking her life for her. She also exposes Toko to some amount of danger by having told her who she really is.
She lies about certain aspects of her involvement with people since she has a relation ship with Kyoshiro that she doesn't tell Zoro about and she says only Toko knows who she really is implying she's also lying to Kyoshiro as well.
She bankrupts those rich arsonists from the capital but also is well aware that they will sell their own families into slavery to please her and she's fine with their entire families also being enslaved as long as she punishes these men.
She tells Zoro that she wants to kill Orochi with her own hands which is markedly different from how Momonosuke presented his goals of defeating Kaido to Luffy. Momonosuke asks Luffy to help him defeat and Luffy says it's a deal if he takes Kaido himself whereas with Hiyori and Zoro, she specifically hears Zoro think to himself that he wants to avenge Yasu but she retorts by saying she's the one who wants to kill Orochi herself. This is not even addressed again as when she offers Zoro Enma, she tells him he should protect Wano and so it's left hanging that she wants Orochi for herself.
All in all, I'd say Hiyori is a Neutral in this department since she's very jaded and does a lot of things out of spite and is clearly lying to maintain her own agenda of some kind. Her heart's in the right place but she's very much not above doing shady things.
Final verdict is Lawful Neutral
For reference I have characters like
Rebecca - Lawful good, Luffy - Chaotic good, Big mom - Chaotic Evil, Doflamingo - Lawful evil.
On the lawful vs Chaos side.
She is very proudly boastful of her Samurai bloodline claiming she would not ask for Orochi's forgiveness for slapping him because it would be too insulting to her Samurai bloodline. So she displays great respect for the honor of noble bloodlines like hers here. This is lawful.
Later she seemingly shows more respect for Wano as a country than her bloodline when she's willing to part with a family heirloom by giving it to Zoro, a relative stranger, in exchange for Shusui, a national treasure, being left in its burial ground. This of course is also Lawful since adherence to the respect given to heirachy in authority is lawful and the Kozuki clan she respects is in service of Wano as a country.
Therefore I would say she's Lawful.
Next is the Good vs Evil part.
She put herself in harms way to save Toko multiple times and she says in her eyes the most despicable thing Orochi has done is prevent from expressing their grief and sorrow through the Smile fruits. This falls along Good since its self sacrifice and empathy.
She suffered from some sort of depression and remained mute after her parents died and Kawamatsu spent the time cheering her up until she was seemingly got over this. Then she ran away since she didn't want to see him waste away from starvation just to feed her which left Kawamatsu heartbroken obviously.
She saved Toko but said "her cheerfulness is what keeps her going" insinuating that she also specfically gains something (probably due to her previous depression) from having Toko around and she isn't entirely altruistic in her risking her life for her. She also exposes Toko to some amount of danger by having told her who she really is.
She lies about certain aspects of her involvement with people since she has a relation ship with Kyoshiro that she doesn't tell Zoro about and she says only Toko knows who she really is implying she's also lying to Kyoshiro as well.
She bankrupts those rich arsonists from the capital but also is well aware that they will sell their own families into slavery to please her and she's fine with their entire families also being enslaved as long as she punishes these men.
She tells Zoro that she wants to kill Orochi with her own hands which is markedly different from how Momonosuke presented his goals of defeating Kaido to Luffy. Momonosuke asks Luffy to help him defeat and Luffy says it's a deal if he takes Kaido himself whereas with Hiyori and Zoro, she specifically hears Zoro think to himself that he wants to avenge Yasu but she retorts by saying she's the one who wants to kill Orochi herself. This is not even addressed again as when she offers Zoro Enma, she tells him he should protect Wano and so it's left hanging that she wants Orochi for herself.
All in all, I'd say Hiyori is a Neutral in this department since she's very jaded and does a lot of things out of spite and is clearly lying to maintain her own agenda of some kind. Her heart's in the right place but she's very much not above doing shady things.
Final verdict is Lawful Neutral
For reference I have characters like
Rebecca - Lawful good, Luffy - Chaotic good, Big mom - Chaotic Evil, Doflamingo - Lawful evil.