zoro was the fastest supernova on the rooftop, so he did what must be done.
law abilities are not instant, he needs time to prepare, it even happened afterward:
Just Oda's way of getting Zoro off the roof when he no longer wanted the narrative that is "Supernova, New generation va Old Generation" on the rooftop in preparation for Luffy's 1vs1
Makes no sense that Law wasn't able to react immediately, look how quickly he teleported the scabbards before Kaido's strike in chapter 1000
Oda need to take out Zoro from the rooftop or else the battle would have ended in 3/4 chapters , unfortunately a single yonko doesn't have the strength to do it so they require to hakai
Zoro took Hakai so he would have to take the Mink medicine for some reason.
Chances are, the reason is that so Zoro can be limited in the next arc to prove how "tough" Onigashima was on the crew. Everyone else will be fine but Oda likes making Zoro the guinea pig for severe injuries so he'll be the one to suffer. He'll be 100% the arc after though, so there's that.
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