Lucci was confident that with him and Kizaru, they were going to steamroll the Straw Hats. That didn't happen, and he sees that not even Kizaru is able to easily deal with Luffy.....
But yeah, I'm sure it's because he fought Zoro for 10 seconds, that he recognized Luffy as a Yonko.
It's because they thought Zoro is near Luffy
That Zoro is top tier
That zoro will low/no diff Lucci
That Zoro will fight Kizaru
That Zoro won't use CoC & Ryuo like Luffy didn't vs awakened Lucci
The problem is that Oda has made it clear Lucci was always >= King and Zoro was always 2/3 tiers below Luffy
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