It's possible that he wanted to become affiliated with the WG.
Kinda what Neptune tried to do with going to the Reverie.
Considering Imu's existence isn't supposed to be public knowledge.
Luffy chose to immediately use G5 against Lucci without feeling out his power first. We can say he simply wanted to test it out some more.
In this chapter they felt the Haki and attack from Gaban and then Zoro even decided to use aCoC right off the bat while Luffy at the same time jumped immediately to G5.
funny how Luffy wants to be left alone with Kaido
meanwhile he has to team up 2v1 with all out Zoro and his peak transformation against old and slow Gaban
I'm sure Lucci didn't embarrass base Luffy to such high levels, like putting the key in Luffy's mouth, easily dodging all his attacks, then making him paniked bcoz of a named attack.
Luffy immediately realised Gaban is powerful and pulled G5. Also, Zoro busted ACoC as well which wasn't the case with Lucci.
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