If you mean in a group effort then sure, but other than that Zoro will have a 1v1 with someone else.
The way things are setting up, it's not going to be 1v1s, but rather groups vs individuals. For example right now let's take the spoilers at face value and assume they aren't just clashes but actual final fights: both Jack and King are taken.
On the Alliance side we have Marco, Zoro, Kidd, Law, Jinbei, Killer who don't have a match up yet. The only really suitable enemy that can match with one of them is Queen, (and then maybe Who's Who, Apoo), anyone else you expect shouldn't cause too much difficulty for them. And if Sanji is going against King, it doesn't make sense for the above named to fight weaker characters.
Clearly there isn't enough around for proper 1v1 match ups.