It's because among the Paramecia, Logia, and Zoan types, ONLY the Logia have primordial entities.
Vegapunk couldn't figure out how to constitute them because their process for creation was on a cosmic scale. He can't replicate that in a laboratory. They are the original forces that constitute reality. How was he supposed to do something like reconstitute darkness when it existed at the very beginning of the creation of the universe?
Scale and Time: The natural processes that forged the elements occurred on a cosmic scale over millions to billions of years, in environments of extreme pressure and temperature like the cores of stars and the immediate aftermath of the Big Bang. We cannot replicate this scale and time frame in a lab.

Vegapunk couldn't figure out how to constitute them because their process for creation was on a cosmic scale. He can't replicate that in a laboratory. They are the original forces that constitute reality. How was he supposed to do something like reconstitute darkness when it existed at the very beginning of the creation of the universe?
Scale and Time: The natural processes that forged the elements occurred on a cosmic scale over millions to billions of years, in environments of extreme pressure and temperature like the cores of stars and the immediate aftermath of the Big Bang. We cannot replicate this scale and time frame in a lab.

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