I feel confident that we pretty much know all the main top tiers in the manga at this point. Elbaf seems like the last major country the SHP will travel to, and we´re pretty regularly seeing the top level of the government now. We see Imu a lot these days, we know about the 5 Gorosei, some Gorosei levelish members of the Gods Knights(Shamrock and Garling.... Maybe Gunko but probably a bit below). We´ve known about the top pirates and marines for awhile now, so all that really leaves is the man marked by flames.
(and Loki can always get stronger as time passes)