The supreme king haki is ambition, it's the character of a person. His mind snapped, it was all for this. Sanji's character development took him to supreme ambition. It's all connected. You can't train supreme king haki, it depends on the person.
It'd be the "right time" with the proper build up and choreography behind Sanji, or Zoro for that instance, unlocking CoC.
At it happened in Elbaf, the whole ordeal was rushed.
The wings were given each an opponent that couldn't be defeated without CoC. A half-assed flashback was slapped mid-fight to explain their psychological background, and then CoC was miraculously awakened.
Man, these cockroaches must be seething everytime Oda once again groups Zoro with Sanji as an asset to Condom and not their idolo being the VC and sole hand and partner of condom
Wings, Gaban, CoC Trio, and now the shield/sword stuff… lmfaoooo
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