Iron man was popular before MCU starts, but he started to grow more during 2000s.
Think about it, every single Marvel animated show or vídeo game had at least one Iron Man cameo.
And became popular in comics during Extremis saga, that was peak Iron Man.
Imagine training your whole life to be WSS swordsman and doesn't fight against a properly swordsman during the whole New World just to the end, defeat the WSS, lol.
Zoro vs Mihawk has legit the worst set up of all time.
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