Usopp vs Killingham could play out similarly to Perona fight. People getting too caught in power scaling here.
I don’t think he outright beats him but he could find a way to undo the nightmare creatures on Elbaf.
I feel like you're vastly overstating Whitebeard's feelings towards Rocks. The crew was a ragtag bunch that were forced into an allegiance and functioned out of mutual interest. He seemed to hold enough fondness to fight side by side with him but it's not remotely close to the loyalty a 1st mate...
Again Gaban specifies CoC is so important in the upcoming battle precisely due to the oppositions immortality. Dorry/Broggy might not have immortality at all, making Zoro/Sanji CoC awakening narratively incongruent if they unlock it against opponents that don't possess immortality.
Yeah I think it's equally possible, I just don't find Dorry and Broggy to be exciting matchups is all.
In fairness, from my recollection it's still in dispute whether Domi Reversi grants regeneration. And the narrative seems to point towards Zoro/Sanji's CoC awakening being a direct answer to...
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