Zoro has his own thing going on in Wano, the all thing with Yasuie got him involved in the inner struggles of Wano and he has a personal vendetta against Orochi. Him going against King makes much more sense. What exactly there's to do with Smoothie? Like I said earlier, the only thing she has...
Out of Doffy's top four Pica was the least significant plot-wise and was solely there to serve as supposedly the strongest weapon that Doffy had in his arsenal, his devil fruit was more significant than him. Zoro vs Pica was a thing only because Oda had to give Zoro something to do while Luffy...
I don't see any reason for it to happen. Oda has made it pretty clear that aside from her position as a sweet commander Smoothie has got no importance to the plot whatsoever.
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