So according to the Ultra Analysis Book these are the rankings for the villains.
S-Rank Villains:
All for One
Gigantomachia
Tomura Shigaraki
Jin Bubaigawara aka Twice
Hood aka High-End
A-Rank Villains:
Rikiya Yotsubashi aka Re-Destro
Dabi
Himiko Toga
Chizome Akaguro aka Stain
Daruma Ujiko...
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