Oda tried a different route with sanji.
He literally turned sanji into a special zoan df lol.
As of now sanji doesn't have CoC let alone adv one but that doesn't mean that his next pu couldn't be CoC. I don't know about the adv form though.
About sanji's will, the difference between him and guys like Zoro or Luffy is only one.
Sanji doesn't afraid to die or even throw away his life for his beliefs or his beloved ones. The difference is that at least for now, that Sanji while he doesn't afraid to die fighting, he doesn't have the attribute of : it doesn't matter if it looks impossible to beat you, or if you beat me 100 times, i will beat you.
This is a trait of kings only.
Luffy has it more than everyone and that is why he will be the king of kings, you can spot this in the manga a couple of times that sanji doesn't have that.
Guys like Luffy, zoro, kid etc believe that they are going to win a fight even if they take an unbelievable beating while guys like Sanji, law, jinbe etc they will die fighting but in their minds know that they will lose but they are true warriors.
Now, even if i am right that doesn't mean that sanji can't be a top tier, law has already entered the league but that's my take about CoC in general.
About adv CoC, is what i said about CoC times 10, hence only the very strongest can have it.