
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Zoro vs Mr1 : finishing with Shishi sonson
Zoro vs Ohm : finishing with pound canon
Zoro vs Kaku : finishing with Asura Ichibugin
Zoro vs Pacifista : finishing with Asura Makyusen
Zoro vs Pica : Ichidai Sanzen daisen Sikai + Sanzen sikai
Zoro vs Kamazou : Purgatory onigiri
Zoro vs Kaido : Asura dead man's game
etc etc not counting the other less popular fights
Every fight we see atleast one or two new moves of Zoro and I just listed the finishing moves, headcanon.com is the sanctuary of every Sanji fan