Mhm. Could easily happen, but I'll say no.
Apoo got to hypetool Luffy and Zoro because he's a Worst Gen member who's been in the series since chapter 499. Chances are high that all he's going to achieve in the series is landing those hits on them then getting beaten off Kid. It's a bit of payoff so he doesn't seem rather pathetic.
For the Flying Six, I clearly have much lower expectations for them than a lot of people here. Functionally, I see no difference between them and other lower ranked opponents in the past- the non-Seat Officers, the lower Doriki CP9, the non M3 opponents in BW. Their main purpose is to beaten by the Alliance, and not even the stronger members. If they never do anything but get beaten in their only fight that wouldn't surprise me in the slightest. I think Sanji vs Page One has already perfectly demonstrated the gap in strength there, and Jinbei has always seemed well above them.
Better to just get the two of them into their main fights where they can really get stuck into their enemies.