Sanji no doubt
Zoro's moment isn't an MVP moment tbh
Tbh Sanji is more of an MVP in Thriller Bark than Zoro, given the amount of things he did and went through in the arc, and still fought Kuma and was ready to make a sacrifice.
Zoro's moment is much more a character moment than an MVP moment, not to mention that Sanji saved Zoro from getting hit by Kuma's laser, so his presence was meaningful since the start
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I don't see a case for Law because there wasn't any real challenges like in TB and Alabasta.