Hitsugaya's adult form can only be accessed after all of his Bankai's ice petals have fallen. (Not sure about that, it's been a long time since I read the manga)
So it takes a considerable amount of time.
But if I ignored that, yes, adult Hitsugaya would undoubtedly be in the most powerful...
Haki can nullify Devil Fruit effects, that's what the work says.
Having stronger haki doesn't necessarily make you stronger than X or Y, if we take that for granted then Vergo is more powerful than characters like Doffy or Queen.
In fact, the Queen himself says he has defeated countless HAKI...
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