I hope Kizaru faces as many of the characters on Egghead as possible so Zoro, Sanji clashing individulally/together and G5 Luffy vs Awakened Kizaru would be wonderful in my opinion.
Zoro needs to pay Kizaru back for Sabaody and Sanji's main task is usually protecting his weaker allies from formidable foes even if they're beyond him. Lots of potential for Kizaru facing any of the Monster Trio. Sanji's invisible speed being handled by Borsalino but recognised and Zoro's haki-coated attacks being dodged efficiently whilst still pressuring non-awakening Kizaru would be reasonable.
With the focus on awakenings this arc, Luffy vs Kizaru just seems essential, but top of Luffy making up for being helpless against Kizaru at Sabaody and Marineford.