Let me make one thing clear, Luffy HAS NOT earned a right to be Zoros captain, if he agrees to Luffy, he does it out of nobility and kindness of heart, and if he disobeys him, he has ALL THE RIGHTS in the world to do so.
Luffy should be so grateful to Zoro for how much Zoro has done for his worthless ass, that if Zoro slaps him in the face and tells him to get the fuck outta ship and let Zoro be the captain, Luffy shouldn't even have right to say no
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Zoro is doing Luffy Charity by being his first mate.