Technically Ryuma would be stronger because Enma has more potential. He would of made Enma a black blade, but none black Enma ain't superior to Shisui.
Zoro would cut kaido with way more difficulty with Shisui
Zoro doesn't know yet how to release large quantities haki, enma is there to tap in his hidden potential, but he can't scar kaido without it until the end of this arc probably
See Zoro cut Kaido twice using Enma and only once did it lead to a perma scar. And in that incident Kaido acknowledged Zoro's Conquerors usage in that attack.
It was Zoro's dormant Conquerors that Enma pulled out (as he was giving his all out on that attack and trying to save his Captain's skull from getting crushed).
Put the same amount of Conquerors onto Shusui and then lets talk. Black blades being stronger than other blades is literally a manga fact.
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