The Nefertari family isn't a D. Queen Lili however wrote a letter about the clan, which means the war was probably between the D. Clan and the 20 Kings.
I bet Lili had the control of ancient Weapon that Imu uses. and he used they used the Opi Opi no mi to seize her body and later to give her internal youth.
basically is the same what Doffy wanted and the secret that he had.
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