You can't affirm that Zoro didn't used adv CoC. But he 100% has CoC so it is possible.
First thing you have to understand that Haki is a mess and not well constructed system. Oda was lost with basic introductions and is even more lost with advanced versions.
Emma has it own presence. Oden was using it before so Kaido assimilate that to Oden presence. Is like there is only one Ferrari in your city and it's from Oden but he let Zoro take a ride on it. Kind of joke but I think you can understand. Actually Emma is more of a old and broken car since it is a nerf.
Zoro has CoC is 100% confirmed. Oden, Roger and if I'm correct WB never showed CoC as Luffy did by knocking out others but they have anyway. Zoro can be like them.
The haki leaking when using adv CoC is very controversial. We didn't saw Zoro leaking at this point. But in Dressrosa his sword leaks a bit. Fact is we didn't saw the panel of Zoro cutting Kaido. Only after. And the same goes to Oden. No haki leaking and no panel of the cut. So Oden didn't knew too?
Also both BM and Kaido are now using but previously we never saw them using or leaking haki.
We have WB x Shanks and BM x Kaido clash touching weapons and not leaking haki. And everybody has the same powers and haki. Only Shanks is not confirmed to have adv CoC but for sure he does. Only Roger and WB clash they weren't touching and leaking haki.
So it is just a mess. Oda just want to hype things up doesn't matter if make any sense or not.
Luffy didn't got hit by Zoro. Kaido did. Kaido never said about coat too. Luffy made his speech after Zoro attack. Maybe he saw Zoro doing it and figured out.
First thing you have to understand that Haki is a mess and not well constructed system. Oda was lost with basic introductions and is even more lost with advanced versions.
Emma has it own presence. Oden was using it before so Kaido assimilate that to Oden presence. Is like there is only one Ferrari in your city and it's from Oden but he let Zoro take a ride on it. Kind of joke but I think you can understand. Actually Emma is more of a old and broken car since it is a nerf.
Zoro has CoC is 100% confirmed. Oden, Roger and if I'm correct WB never showed CoC as Luffy did by knocking out others but they have anyway. Zoro can be like them.
The haki leaking when using adv CoC is very controversial. We didn't saw Zoro leaking at this point. But in Dressrosa his sword leaks a bit. Fact is we didn't saw the panel of Zoro cutting Kaido. Only after. And the same goes to Oden. No haki leaking and no panel of the cut. So Oden didn't knew too?
Also both BM and Kaido are now using but previously we never saw them using or leaking haki.
We have WB x Shanks and BM x Kaido clash touching weapons and not leaking haki. And everybody has the same powers and haki. Only Shanks is not confirmed to have adv CoC but for sure he does. Only Roger and WB clash they weren't touching and leaking haki.
So it is just a mess. Oda just want to hype things up doesn't matter if make any sense or not.
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Luffy talks about Kaidou though, not Zoro. Kaidou just said Zoro is a CoC user and no wonder Zoro can scar him (give damage), nothing about CoC coating